POPs (Persistent Organic Pollutants) are a group of organic pollutants, either naturally occurring or synthetically produced, that are characterized by long-term persistence, bioaccumulation, semi-volatility, and high toxicity. These substances can travel long distances through environmental media such as air, water, and living organisms, posing serious risks to human health and the environment.
Recently, the United Kingdom introduced two amendments:
1. The Persistent Organic Pollutants (Amendment) Regulations 2023 (UK SI 2023/729)
- Effective date: July 4, 2023
- Amendment: The deadline for the use of oil- and water-repellent textiles designed to protect workers from hazardous liquids was extended from July 4, 2023, to December 3, 2025.
2. The Persistent Organic Pollutants (Amendment) (No. 2) Regulations 2023 (UK SI 2023/1217)
- Effective date: November 16, 2023
- Amendment: Introduced new restrictions on Perfluorohexane sulfonic acid (PFHxS), its salts, and related substances, aligning with EU legislation.
On April 14, 2025, the European Commission adopted a draft amendment to Regulation (EU) 2019/1021 concerning restrictions on Perfluorooctane Sulfonic Acid (PFOS). The official effective date will be announced upon its publication in the EU Official Journal.
- Chemical identification: PFOS and its salts, derivatives (C8F17SO2X, where X = −OH, metal salt (O−M+), halide, amide, or other related compounds including polymers).
- Revised restriction conditions:
1. The concentration of PFOS or any of its salts in a substance, mixture, or article must not exceed 0.025 mg/kg (0.0000025% by weight).
2. The total concentration of all PFOS-related compounds in substances, mixtures, or articles must not exceed 1 mg/kg (0.0001% by weight).
3. Articles containing PFOS that were already in use before August 25, 2010, may continue to be used. This provision remains unchanged.
4. Former conditions (4) and (5) have been removed from the regulation.
5. The scope now explicitly includes PFOS, its salts, and all related compounds with the general formula C8F17SO2X.
PFOS is known for its oil-repellent, water-repellent, and anti-stain properties. It has been widely used in the surface treatment of textiles, leather, furniture, and carpets to provide waterproof, oil-resistant, and stain-resistant characteristics. Due to its chemical stability, PFOS has also been used as an intermediate in the manufacture of coatings, firefighting foams, floor treatments, food contact materials, and especially non-stick cookware coatings.
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